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1868 ( MDCCCLXVIII) was a leap year starting on Wednesday of the Gregorian calendar and a leap year starting on Monday of the Julian calendar, the 1868th year of the Common Era (CE) and (AD) designations, the 868th year of the Anno Domini 2nd millennium, the 68th year of the 19th century, and the 9th year of the 1860s decade. As of the start of 1868, the Gregorian calendar was 12 days ahead of the Julian calendar, which remained in localized use until 1923.
January 2 – British Expedition to Abyssinia: Robert Napier leads an expedition to free captive British officials and missionaries. 
January 3 – The 15-year-old Mutsuhito, Emperor Meiji of Japan, declares the , his own restoration to full power, under the influence of supporters from the Meiji Restoration Ch?sh? and Satsuma Domains, and against the supporters of the Tokugawa shogunate, triggering the Boshin War.  
January 5 – Paraguayan War: Brazilian Army commander Luís Alves de Lima e Silva, Duke of Caxias enters Asunción, Paraguay's capital. Some days later he declares the war is over. Nevertheless, Francisco Solano López, Paraguay's president, prepares guerrillas to fight in the countryside.
January 7 – The Arkansas constitutional convention meets in Little Rock.
January 9 – Penal transportation from Britain to Australia ends, with arrival of the convict ship in Western Australia, after an 89-day voyage from England. There are 62 Hougoumont Fenians among the transportees.
January 10 – Sh?gun Tokugawa Yoshinobu declares the emperor's declaration "illegal", and prepares to attack Kyoto.
January 27– 31 – Battle of Toba-Fushimi: forces of the Tokugawa shogunate and the allied pro-Imperial forces of the Ch?sh?, Satsuma and Tosa Domains clash near Fushimi, Kyoto, ending in a decisive victory for the Imperial forces (although in the January 28 naval Battle of Awa, the Shogunate is victorious against Satsuma).
February – Foreign ministers meeting in Hy?go are persuaded to recognise the restored Emperor Meiji of Japan, with promises that harbours will be open in accordance with international treaties. 
February 13 – The British War Office sanctions the formation of what becomes the Army Post Office Corps.
February 16 – In New York City the Jolly Corks organization is renamed the (BPOE). Benevolent and Protective Order of Elks
February 19 – In the Passage of Humaitá, a Brazilian naval force succeeds in dashing past a Paraguayan fortress on the River Paraguay, considered by some the turning point in the Paraguayan War.
March – French geologist Louis Lartet discovers the first identified skeletons of Cro-Magnon, the first early modern humans (early Homo sapiens sapiens), at Abri de Crô-Magnon, a rock shelter at Les Eyzies, Dordogne, France.
March 23 – The University of California is founded in Oakland, California, when the Organic Act is signed into California law.
March 24 – The Metropolitan Life Insurance Company is formed, in New York City.
March 27 – The Lake Ontario Shore Railroad Company is organized in Oswego, New York. March – The first transnational women's organization, , is founded. Association internationale des femmes
April 1 – The Hampton Normal and Agricultural Institute is established in Hampton, Virginia.
April 7 – The Charter Oath, drawn up by his councilors, is promulgated at the enthronement of the Emperor Meiji of Japan, promising deliberative assemblies and an end to feudalism. 
April 9 – Emperor Tewodros II of Ethiopia massacres at least 197 of his own people at Magdala. These are prisoners incarcerated, for the most part, for very trivial offenses, and are killed for requesting bread and water.
April 9– 13 – Battle of Magdala: A British-Indian task force under Robert Napier inflicts 700 deaths and a crushing defeat on the army of Emperor Tewodros II; the British and Indians suffer 30 wounded, two of whom die subsequently. Tewodros commits suicide and Magdala is captured, ending the British Expedition to Abyssinia.
April 11 – July – Fall of Edo: The Japanese city surrenders to Emperor Meiji. Sh?gun Tokugawa Yoshinobu submits to the Emperor.
April 29 – General William Tecumseh Sherman brokers the Treaty of Fort Laramie, between the federal government of the United States and the Plains Indians.
May 10– 14 – Boshin War – Battle of Utsunomiya Castle, Japan: Forces of the Emperor Meiji resist the retreating troops of the Tokugawa shogunate.
May 16, May 26 – President Andrew Johnson is twice acquitted during his impeachment trial, by one vote in the United States Senate.
May 26 – Fenian bomber Michael Barrett becomes the last person publicly hanged in the United Kingdom.
May 29 – The Parliament of the United Kingdom passes the Capital Punishment Amendment Act, thus ending public hanging.
May 30 – Memorial Day is observed in the United States for the first time (it was proclaimed on May 5 by General John A. Logan).
June – T?tokowaru's War breaks out in the South Taranaki District of New Zealand's North Island between the Ng?ti Ruanui M?ori tribe and the New Zealand Government.
June 1 – The Treaty of Bosque Redondo is signed, allowing the Navajo to return to their lands in Arizona and New Mexico.
June 2 – The first Trades Union Congress is held in Manchester, England.
June 10 – Mihailo Obrenovi?, Prince of Serbia is assassinated in Ko?utnjak, Belgrade. June 20 – Fort Fred Steele is established to protect what is at this time the western terminus of the Union Pacific Railway, near modern-day Sinclair, Wyoming.
July 1 – The cable-operated West Side and Yonkers Patent Railway in Manhattan becomes the first elevated railway in the United States.
July 4 – Battle of Ueno: Imperial Japanese troops defeat the Sh?gitai (elite forces remaining loyal to the ). sh?gun
July 5 – Preacher William Booth establishes the Christian Mission, predecessor of The Salvation Army, in the East End of London.
July 9 – The Fourteenth Amendment to the United States Constitution is ratified.
July 18 – The Navajo people begin their long march home.
July 25 – Wyoming becomes a United States territory.
July 25 – Paraguayan War: The Allies, in an amphibious operation, capture the fortress of Humaitá.
July 27 – The United States Expatriation Act ("An Act concerning the Rights of American Citizens in foreign States") is adopted. 
July 28 – The Fourteenth Amendment to the United States Constitution is adopted, including the Citizenship Clause and the Equal Protection Clause, legally, if not actually, guaranteeing African Americans full citizenship and equal protection, and all persons in the United States due process of law.
August 13 – The 8.5-9.0 Arica earthquake strikes southern Peru, with a maximum Mercalli intensity of XI ( Extreme), causing 25,000+ deaths and a destructive basin-wide tsunami, that affects Hawaii and New Zealand.
August 18 – The element later named as helium is first detected in the spectrum of the Sun's chromosphere, by French astronomer Jules Janssen, during a total eclipse in Guntur, British India, but is assumed to be sodium. 
August 20 – Abergele rail disaster in Wales: An Irish Mail passenger train collides with 4 cargo trucks loaded with paraffin oil (more akin to modern kerosine); 33 are killed (the first major train disaster in Britain).
August 22 – The Yangzhou riot in China targets a station of the China Inland Mission, and nearly leads to war between Britain and China.
September – Glorious Revolution: Queen Isabella II of Spain is effectively deposed and sent into exile; she formally abdicates on June 25, 1870.
September 3 – Emperor Meiji of Japan announces that the name of the city of Edo is to be changed to Tokyo.
September 7 – T?tokowaru's War: M?ori leader Titokowaru defeats a New Zealand military force at Te Ngutu o Te Manu, North Island.
September 18 – The University of the South holds its first convocation in Sewanee, Tennessee.
September 23 – Grito de Lares: Rebels (some 400-600 led by Ramón Emeterio Betances) in the town of Lares declare Puerto Rico independent; the local militia easily defeats them a week later. September 24 – Croatian-Hungarian Settlement ( Croatian: Hrvatsko-ugarska nagodba, Hungarian: Horvát-magyar kiegyezés, German: Kroatisch-Ungarischer Ausgleich) is concluded, governing Croatia's political status in the Hungarian-ruled part of Austria-Hungary until 1918. 
January 1 – Snitz Edwards, Hungarian-born actor (d. 1937)
January 6 – Vittorio Monti, Italian composer (d. 1922)
January 9 – S. P. L. Sørensen, Danish chemist (d. 1939)
January 11 – Cai Yuanpei, Chinese educator (d. 1940)
January 15 – Otto von Lossow, Bavarian and German general (d. 1938)
January 18 – Kantar? Suzuki, 29th Prime Minister of Japan (d. 1948)
January 21 – Felix Hoffmann, German chemist (d. 1946)
January 31 – Theodore William Richards, American chemist, Nobel Prize laureate (d. 1928)
February 4 – Constance Markievicz, Irish politician (d. 1927) 
February 5 – Maxine Elliott, American actress (d. 1940)
February 10 – William Allen White, American journalist (d. 1944)
February 12 – William Faversham, English actor (d. 1940)
February 16 – Edward S. Curtis, American photographer, ethnologist, and film director (d. 1952)
February 23 – W. E. B. Du Bois, African American civil rights leader (d. 1963) 
February 25 – Constantin Dumitrescu, Romanian general (d. 1935)
February 26 – Venceslau Brás, Brazilian president (d. 1966)
March 1 – Adolf von Trotha, German admiral (d. 1940)
March 14 – Emily Murphy, Canadian woman's rights activist (d. 1933)
March 22 – Robert Andrews Millikan, American physicist, Nobel Prize laureate (d. 1953)
March 25 – Bill Lockwood, English cricketer (d. 1932)
March 28 – Maxim Gorky, Russian author (d. 1936)  March 29 – Joseph Cawthorn, American actor (d. 1949)
April 1 – Edmond Rostand, French poet and playwright (d. 1918) 
April 10 – George Arliss, English actor (d. 1946)
April 12 – Akiyama Saneyuki, Japanese admiral (d. 1918)
April 17 – Zde?ka Wiedermannová-Moty?ková, Moravian pioneer of female education (d. 1915)
May 12 – Al Shean, German-born actor (d. 1949)
May 21 – John L. Hines, American general, Chief of Staff of the U.S. Army (d. 1968)
May 29 – Abdülmecid II, last Caliph of the Ottoman Empire (d. 1944)
June 5 – James Connolly, Irish-Scots socialist (d. 1916)
June 6 – Robert Falcon Scott, English Antarctic explorer (d. 1912) 
June 18 – Miklós Horthy, Austro-Hungarian admiral and regent of the Kingdom of Hungary (d. 1957)
July 2 – Traian Mo?oiu, Romanian general and politician (d. 1932)
July 4 – Henrietta Swan Leavitt, American astronomer (d. 1921)
July 12 – Stefan George, German poet (d. 1933)
July 14 – Gertrude Bell, English archaeologist, writer, spy and administrator (d. 1926) 
July 15 – Nobuyoshi Mut?, Japanese field marshal and ambassador (d. 1933)
July 19 – Florence Foster Jenkins, American socialite and amateur operatic soprano (d. 1944) 
July 20 – Patriarch Miron of Romania, 38th Prime Minister of Romania (d. 1939)
July 24 – Princess Srivilailaksana The Princess of Suphanburi daughter of King Chulalongkorn of Siam and Chao Chom Manda Pae Bunnag (d. 1904)
July 28 – Theodor Wulf, German physicist and Jesuit (d. 1946)
August 5 – Oskar Merikanto, Finnish composer (d. 1924)
August 6 – Paul Claudel, French poet, dramatist and diplomat (d. 1955) 
August 7 – Martin Wetzer, Finnish general (d. 1954)
August 10 – Hugo Eckener, German dirigible engineer, Commander of (d. Graf Zeppelin I 1954)
August 23 – Edgar Lee Masters, American poet, biographer and dramatist (d. 1950)
August 26 – Charles Stewart, Premier of Alberta (d. 1946)
September 1 – Henri Bourassa, Canadian politician and publisher (d. 1952)
September 6 – Heinrich Häberlin, Swiss politician, member of the Federal Council (d. 1947)
September 8 – Seth Weeks, African American jazz mandolinist, composer, arranger and bandleader (d. 1953)
September 9 – Mary Hunter Austin, American writer of fiction and non-fiction (d. 1934)
September 17 – James Alexander Calder, Canadian politician (d. 1956) September 22 – John T. Raulston, American state judge (Scopes Monkey Trial) (d. 1956)
October 4 – Marcelo Torcuato de Alvear, President of Argentina (d. 1942)
October 18 – Ernst Didring, Swedish writer (d. 1931)
October 21 – Ernest Swinton, British Army general (d. 1951)
October 24 – Alexandra David-Néel, French explorer (d. 1969)
October 30 – António Cabreira, Portuguese polygraph (d. 1953) 
November 7 – Delfim Moreira, Brazilian president (d. 1920)
November 8 – Felix Hausdorff, German mathematician (d. 1942)
November 9 – Marie Dressler, Canadian actress (d. 1934)
November 14 – Steele Rudd, Australian author (d. 1935)
November 17 – Korbinian Brodmann, German neurologist (d. 1918)
November 22 – John Nance Garner, 32nd Vice President of the United States (d. 1967)
November 23 – Mary Brewster Hazelton, American portrait painter (d. 1953)
November 30 – Ernest Newman, English music critic (d. 1959)
December 5 – Arnold Sommerfeld, German theoretical physicist (d. 1951)
December 9 – Fritz Haber, German chemist, Nobel Prize laureate (d. 1934)
December 19 – Eleanor H. Porter, American novelist (d. 1920) 
December 20 – Arturo Alessandri, Chilean statesman, 3-Time President of Chile (d. 1950)
December 21 – George W. Fuller, American sanitation engineer (d. 1934)
December 22 – Jaan Tõnisson, 2nd Prime Minister of Estonia (d. 1941?)
December 25 – Eugenie Besserer, American silent film actress (d. 1934) probable – Scott Joplin, African American ragtime composer and pianist (d. 1917) 
January 20 – Damien Marchesseault, 7th Mayor of Los Angeles (suicide) (b. 1818)
January 23 – János Erdélyi, Hungarian poet and ethnographer (b. 1814)
January 28 – Adalbert Stifter, Austrian writer (b. 1805)
February 8 – Lai Wenguang, Chinese leader of the Taiping Rebellion and Nien Rebellion (b. 1827)
February 10 – Sir David Brewster, Scottish physicist (b. 1781)
February 11 – Léon Foucault, French physicist (b. 1819) 
February 19 – Venancio Flores, Uruguayan general and president of Uruguay (b. 1808)
February 29 – King Ludwig I of Bavaria (b. 1786) 
March 4 – Jesse Chisholm, American pioneer (b. 1805)
March 19 - Philipp von Stadion und Thannhausen, Austrian field marshal (b. 1799)
March 28 – James Brudenell, 7th Earl of Cardigan, British military leader (b. 1797)
April 3 – Franz Berwald, Swedish composer (b. 1796) 
April 7 – Thomas D'Arcy McGee, Canadian father of confederation (assassinated) (b. 1825)
April 12 – James Gascoyne-Cecil, 2nd Marquess of Salisbury, British politician and peer (b. 1791)
April 13 – Emperor Theodore or Tewodros II of Ethiopia by suicide (b. 1818)
April 21 – Henry O'Farrell, Irish-Australian criminal (executed) (b. 1833)
May 7 – Henry Brougham, 1st Baron Brougham and Vaux, Lord High Chancellor of Great Britain (b. 1778) May 10 – Henry Bennett, American politician (b. 1808)
May 11 – John Crawfurd, Scottish physician, colonial administrator, diplomat and author, last British Resident of Singapore (b. 1783)
May 17 – Isami Kondo, Commander of the Shinsengumi (b. 1834)
May 22 – Julius Plücker, German mathematician and physicist (b. 1801)
May 23 – Kit Carson, American trapper, scout, and Indian agent (b. 1809) 
June 1 – James Buchanan, 15th President of the United States (b. 1791) 
June 10 – Princess Anka Obrenovi?, Serbian princess (b. 1821)
June 22 – Heber C. Kimball, Latter Day Saint leader (b. 1801) June 29 – Sir John Lillie, British army officer, entrepreneur and inventor (b. 1790)
July 6 – Harada Sanosuke, Shinsengumi Captain (b. 1840)
July 19 – Okita S?ji, Shinsengumi Captain (b. 1842 or 1844)
July 21 – William Bland, Australian politician (b. 1789)
July 26 – Robert Rolfe, 1st Baron Cranworth, English Lord High Chancellor of Great Britain (b. 1791)
July 29 – John Elliotson, English physician (b. 1791)
August 3 – Edward Welch, Welsh architect (b. 1806)
August 10 – Adah Isaacs Menken, American actress (b. 1835)
August 11 – Thaddeus Stevens, American politician (b. 1792)
August 25 – Charlotte Birch-Pfeiffer, German actress, writer and theater director (b. 1799)
August 29 – Christian Friedrich Schönbein, German chemist (b. 1799)
September 1 – Ferenc Gyulay, Hungarian nobleman, general and governor (b. 1799)
September 9 – Mzilikazi, first king of Mthwakazi (b. c.1790)
September 11 – Maria James, Welsh-born American poet (b. 1793)
September 19 – William Sprague, American minister and politician from Michigan (b. 1809)
September 26 – August Ferdinand Möbius, German mathematician and astronomer (b. 1790)
October 1 – Mongkut (Rama IV), King of Siam ( Thailand) (b. 1804)
October 9 – Howell Cobb, American politician (b. 1815)
October 17 – Laura Secord, Canadian patriot (b. 1775)
October 27 – Charles Longley, Archbishop of Canterbury (b. 1794)
November 13 – Gioachino Rossini, Italian composer (b. 1792) 
November 15 – James Mayer de Rothschild, German-born banker (b. 1792)
November 27 – Chief Black Kettle, Southern Cheyenne Peace Chief, Survivor of Sand Creek massacre (b. 1803)
December 6 – August Schleicher, German linguist (b. 1821)
December 23 – Sir Herbert Edwardes, British army general and colonial administrator (b. 1819)
December 25 – Linus Yale, Jr., American inventor (b. 1821) December 31 – Cyrus Kingsbury, American missionary and Choctaw linguist (b.1786)
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