|Preferred IUPAC name|
|Systematic IUPAC name
3D model (JSmol)
CompTox Dashboard (EPA)
|Molar mass||80.91 g/mol|
|Density||3.6452 kg/m3 (0 °C, 1013 mbar)|
|Melting point||-86.9 °C (-124.4 °F; 186.2 K)|
|Boiling point||-66.8 °C (-88.2 °F; 206.3 K)|
|221 g/100 mL (0 °C) |
204 g/100 mL (15 °C)
193 g/100 mL (20 °C)
130 g/100 mL (100 °C)
|Solubility||Soluble in alcohol, organic solvents|
|Vapor pressure||2.308 MPa (at 21 °C)|
|Acidity (pKa)||-8.8 (±0.8); ~-9|
Refractive index (nD)
Heat capacity (C)
Std enthalpy of
|Safety data sheet||hazard.com|
|GHS Signal word||Danger|
|P261, P280, P305+351+338, P310|
|NFPA 704 (fire diamond)|
|Lethal dose or concentration (LD, LC):|
LC50 (median concentration)
|2858 ppm (rat, 1 h)|
814 ppm (mouse, 1 h)
|NIOSH (US health exposure limits):|
|TWA 3 ppm (10 mg/m3)|
|TWA 3 ppm (10 mg/m3)|
IDLH (Immediate danger)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
|what is ?)(|
Hydrogen bromide is the diatomic molecule with the formula HBr. It is a colorless compound and a hydrogen halide. Hydrobromic acid is a solution of HBr in water. Both the anhydrous and aqueous solutions of HBr are common reagents in the preparation of bromide compounds.
HBr is very soluble in water, forming hydrobromic acid solution, which is saturated at 68.85% HBr by weight at room temperature. Aqueous solutions that are 47.6% HBr by mass form a constant-boiling azeotrope mixture that boils at 124.3 °C. Boiling less concentrated solutions releases H2O until the constant-boiling mixture composition is reached.
Hydrogen bromide and hydrobromic acid are important reagents in the production of inorganic and organic bromine compounds. The free-radical addition of HBr to alkenes gives alkyl bromides:
Allyl bromide is prepared by treating allyl alcohol with HBr:
Although not widely used industrially, HBr adds to alkenes to give bromoalkanes, an important family of organobromine compounds. Similarly, HBr adds to haloalkene to form a geminal dihaloalkane. (This type of addition follows Markovnikov's rule):
HBr has been proposed for use in a utility-scale flow-type battery.
Hydrogen bromide (along with hydrobromic acid) is produced by combining hydrogen and bromine at temperatures between 200 and 400 °C. The reaction is typically catalyzed by platinum or asbestos.
Concentrated sulfuric acid is less effective because it oxidizes HBr to bromine:
The acid may be prepared by:
Hydrogen bromide prepared by the above methods can be contaminated with Br2, which can be removed by passing the gas through a solution of phenol at room temperature in tetrachloromethane or other suitable solvent (producing 2,4,6-tribromophenol and generating more HBr in the process) or through copper turnings or copper gauze at high temperature.
HBr is highly corrosive and irritating to inhalation.