|Systematic IUPAC name
3D model (JSmol)
CompTox Dashboard (EPA)
Pungent, fruity odor
|Density||0.81 g cm-3|
|Melting point||-81 °C (-114 °F; 192 K)|
|Boiling point||46 to 50 °C (115 to 122 °F; 319 to 323 K)|
|20 g/100 mL|
|Viscosity||0.6 cP at 20 °C|
|C1, O: sp2|
C2, C3: sp3
|R-phrases (outdated)||R11, R36/37/38|
|S-phrases (outdated)||S9, S16, S29|
|NFPA 704 (fire diamond)|
|Flash point||-26 °C (-15 °F; 247 K)|
|175 °C (347 °F; 448 K)|
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
|what is ?)(|
Propionaldehyde or propanal is the organic compound with the formula CH3CH2CHO. It is a saturated 3-carbon aldehyde and is a structural isomer of acetone. It is a colorless liquid with a slightly irritating, fruity odor.
In this way, several hundred thousand tons are produced annually.
Propionaldehyde may also be prepared by oxidizing 1-propanol with a mixture of sulfuric acid and potassium dichromate. The reflux condenser contains water heated at 60 °C, which condenses unreacted propanol, but allows propionaldehyde to pass. The propionaldehyde vapor is immediately condensed into a suitable receiver. In this arrangement, any propionaldehyde formed is immediately removed from the reactor, thus it does not get over-oxidized to propionic acid.
It is principally used as a precursor to trimethylolethane (CH3C(CH2OH)3) through a condensation reaction with formaldehyde; this triol is an important intermediate in the production of alkyd resins. Other applications include reduction to propanol and oxidation to propionic acid.
Condensation of propionaldehyde with tert-butylamine gives CH3CH2CH=N-t-Bu, a three-carbon building block used in organic synthesis. Deprotonation of this imine with LDA produces CH3CHLiCH=N-t-Bu, which in turn condenses with aldehydes.
On 30 July 2015, scientists reported that upon the first touchdown of the Philae lander on comet 67/P surface, measurements by the COSAC and Ptolemy instruments revealed sixteen organic compounds, four of which were seen for the first time on a comet, including acetamide, acetone, methyl isocyanate and propionaldehyde.